"The reason traditional plastics are not biodegradable is because their long polymer molecules are too large and too tightly bonded together to be broken apart and assimilated by decomposer organisms. However, plastics based on natural plant polymers derived from wheat or corn starch have molecules that are readily attacked and broken down by microbes."
Plastics can be produced with starch and even bacteria...unfortunately these alternatives (PLA & PHA) are "significantly more expensive to produce and, as yet, [are] not having any success in replacing the widespread use of traditional petrochemical plastics."
"Indeed, biodegradable plastic products currently on the market are from 2 to 10 times more expensive than traditional plastics. But environmentalists argue that the cheaper price of traditional plastics does not reflect their true cost when their full impact is considered. For example, when we buy a plastic bag we don’t pay for its collection and waste disposal after we use it. If we added up these sorts of associated costs, traditional plastics would cost more and biodegradable plastics might be more competitive."
(Sources: Australian Academy of Science: Making packaging greener – biodegradable plastics)
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